DOI: 10.15507/2658-4123.036.202602.392-415
UDK 621.436.1
Reduction of Smoke and Soot Formation in a Diesel Engine by Replacing Completely Petroleum Fuel with Methanol and Methyl Ester of Rapeseed Oil
Vitaly A. Likhanov
Dr.Sci. (Eng), Professor, Head of the Department of Heat Engines, automobiles and Tractors, Vyatka State Agrotecnological University (133 Oktyabrsky Ave., Kirov 610017, Russian Federation), ORCID: https://orcid.org/0000-0003-3033-7176, Researcher ID: AGN-7347-2022, Scopus ID: 57197821797, SPIN-code: 9474-7629, This email address is being protected from spambots. You need JavaScript enabled to view it.
Oleg P. Lopatin
Dr.Sci. (Eng), Associate Professor, Professor of the Department of Heat Engines, automobiles and Tractors, Vyatka State Agrotecnological University (133 Oktyabrsky Ave., Kirov 610017, Russian Federation), ORCID: https://orcid.org/0000-0002-0806-6878, Researcher ID: AAD-8374-2019, Scopus ID: 57197821205, SPIN-code: 8716-0189, This email address is being protected from spambots. You need JavaScript enabled to view it.
Abstract
Introduction. The characteristics of diesel fuel, including its chemical composition and physico-chemical properties, directly correlate with the engine operation environmental aspects. They determine the soot formation intensity in combusting and soot emissions into the atmosphere with exhaust gases. When an engine operates using alternative biofuels in different load and speed modes, the fuel combustion conditions in the diesel cylinder vary depending on the injection and spraying parameters and the droplet size of the biofuel used that leads to the modification of the soot emission characteristics. The relevance of studying the soot formation in diesel biofuel-powered engines is caused by its direct effect on combustion efficiency, the level of toxic emissions, and on the economic and environmental engine characteristics.
Aim of the Study. The study is aimed at investigating the effect of methanol and methyl ester of rapeseed oil on forming soot and reducing smoke content of diesel engine exhaust gases.
Materials and Methods. The adequacy and topicality of experimental data processing methods is confirmed by experimental studies and analytical dependencies. Experimental studies were conducted according to the GOST 18509-88 methodology, the samples to determine the smoke content of exhaust gases were taken according to the GOST 24028-2013, GOST 17.2.2.02-98, GOST R 41.24-2003 methods. The parameters of the combustion process were determined according to the methods of the Central Scientific Research Diesel Institute, the calculated characteristics of soot were determined according to the Central Research Diesel Institute, Peter the Great St. Petersburg Polytechnic University methods and the Vyatka State Agrotechnological University programs.
Results. There have been studied the morphology and microstructure of aggregate soot particles. There have been considered the physicochemical characteristics of the fuels used in a diesel engine. When operating in the main load and speed modes of a diesel engine running on methanol and methyl ether of rapeseed oil, there have been found exhaust smoke values, temperatures in the zones of soot formation and burnout, the number and diameter of soot particles, the mass content and concentration of soot. There have been also found their maximum values and has been determined the corresponding angle of crankshaft rotation. In the course of the study, the complete replacement of standard petroleum diesel fuel in diesel engines with methanol and methyl ester of rapeseed oil was successfully carried out.
Discussion and Conclusion. The study confirms the possibility to replace completely the standard fuel for the diesel engine with methanol and methyl ester of rapeseed oil that reduces significantly exhaust smoke. The calculated values of the soot concentration in the cylinder correspond to current theoretical models describing the processes occurring inside the cylinder, and are confirmed by the experimental data of the exhaust smoke measurements. Further research areas may include adapting the alternative fuel used and optimizing the fuel supply system of a diesel engine to achieve the lowest possible level of exhaust smoke.
Keywords: soot formation, soot particles, exhaust smoke, diesel engine, methanol, methyl ester of rapeseed oil
Conflict of interest: The authors declare that there is no conflict of interest.
For citation: Likhanov V.A., Lopatin O.P. Reduction of Smoke and Soot Formation in a Diesel Engine by Replacing Completely Petroleum Fuel with Methanol and Methyl Ester of Rapeseed Oil. Engineering Technologies and Systems. 2026;36(2):392–415. https://doi.org/10.15507/2658-4123.26362.392-415
Authors contribution:
V. A. Likhanov – oversight and leadership responsibility for the research activity planning and execution, including mentorship external to the core team; application of statistical, mathematical, computational, or other formal techniques to analyse or synthesize study data; preparation, creation and / or presentation of the published work by those from the original research group, specifically critical review, commentary or revision – including pre- or post-publication stages.
O. P. Lopatin – conducting a research and investigation process, specifically performing the experiments, or data/evidence collection; development or design of methodology; creation of models; preparation, creation and / or presentation of the published work, specifically visualization / data presentation.
All authors have read and approved the final manuscript.
Submitted 10.11.2025;
revised 25.12.2025;
accepted 20.01.2026
REFERENCES
- An Ya., Zhang Yu., Chen T., Shi M., Wang Yu., Su Zh., et al.Numerical Study of Ducted Fuel Injection Strategy for Soot Emissions Reduction in a Heavy-Duty Diesel Engine. Applied Thermal Engineering. 2025;260:125066. https://doi.org/10.1016/j.applthermaleng.2024.125066
- Wang D., Bao G., He Ch., Li J., Chen Ya., Zhao L., et al. Investigation of the Impact of Combustion Chamber Geometry on Engine Combustion and Emission Performance Under Various Fuel Injection Timings with Biodiesel Blending. Energy Science & Engineering. 2025;13(1):268–289. https://doi.org/10.1002/ese3.2000
- Pham D.T., Mai D.N., Ho D.T. Restrict Toxic Emissions from Internal Combustion Engines to Protect the Environment by using Diesel Fuel Mixed with Vegetable Oil. Journal of Environmental and Earth Sciences. 2025;7(2):62–75. https://doi.org/10.30564/jees.v7i2.7693
- Ahmed B.M., Luo M., Elbadawi H.A.M., Mahmoud N.M., Sui P.-Ch. Experimental Study of 2-Ethylhexyl Nitrate Effects on Engine Performance and Exhaust Emissions of Diesel Engine Fueled with Diesel-2-Methylfuran Blends. Energies. 2025;18(1):98. https://doi.org/10.3390/en18010098
- Agarwal S., Yadav A., Mudgal A., Khan S. Comparative Evaluation of Diesel Engine Performance and Emission Characteristics using Carbon Nanotubes & Graphene Oxide in Ternary Fuel (Jojoba Biodiesel-Diesel-Methanol) Blends. Next Research. 2025;2(1):100141.https://doi.org/10.1016/j.nexres.2025.100141
- Rahim Ab.A., Saad I., Mohd Zulkifli N.W., Mohd Yusoff M.N.A. Performance and Emissions of Dual Alcohol Fuel Blend with B20 POME Biodiesel in Diesel Engine. Sciences and Engineering. 2025;87(3):455–463. https://doi.org/10.11113/jurnalteknologi.v87.21791
- Yadav G.P.K., Muvvala P., Reddy R.M. Optimization of Injection Parameters, and Ethanol Shares for Cottonseed Biodiesel Fuel in Diesel Engine Utilizing Artificial Neural Network (ANN) and Taguchi Grey Relation Analysis (GRA). Journal of Non-Equilibrium Thermodynamics. 2025;50(3). https://doi.org/10.1515/jnet-2024-0095
- Hamzah A.H., Akroot A., Wahhab H.A.A. Effect of Nanoparticles and Biodiesel Blended with Diesel on Combustion Parameters in Compression Ignition Engine: Numerical Analysis. Energy Engineering. 2025;122(5):2059–2075. https://doi.org/10.32604/ee.2025.061592
- No S.Y. Utilization of Pentanol as Biofuels in Compression Ignition Engines. Frontiers in Mechanical Engineering. 2020;(6). https://doi.org/10.3389/fmech.2020.00015
- Gupta P., Dixit J., Bhoi R., Sharma D., Sharma N. Investigating the Effect of Using Butyl Palmitate as a Fuel Additive on Diesel Engine Performance, Combustion, Emission, and Soot Morphological
- Characteristics. Journal of Energy Engineering. 2025;151(3). https://doi.org/10.1061/jleed9.eyeng-5817
- Likhanov V.A., Lopatin O.P. Biofuels or smoking cars? Teoreticheskaya i prikladnaya ekologiya. 2021;(3):228–236. (In Russ., abstract in Eng.) https://doi.org/10.25750/1995-4301-2021-3-228-236
- Cabarcos A., Paz C., Pérez-Orozco R., Vence J. An Image-Processing Algorithm for Morphological Characterisation of Soot Agglomerates from TEM Micrographs: Development and Functional Description. Powder Technology. 2022;401:117275. https://doi.org/10.1016/j.powtec.2022.117275
- Lee K.O., Zhu J. Effects of Exhaust System Components on Particulate Morphology in a Lightduty Diesel Engine. In: SAE Transactions. Detroit: SAE International; 2005. pp. 52–60. https://doi.org/10.4271/2005-01-0184
- Adamska K., Smykała S., Zieliński S., Szymański D., Hojeńska A., Stelmachowski P., et al. Oxidation of Soot Over Supported RuRe Nanoparticles Prepared by the Microwave-Polyol Method. Reaction Kinetics, Mechanisms and Catalysis. 2021;(134):221–242. https://doi.org/10.1007/s11144-021-02048-y
- Eigentler F., Gerlinger P. A Detailed PAH and Soot Model for Complex Fuels in CFD Applications. Flow, Turbulence and Combustion. 2022;(109):225–251. https://doi.org/10.1007/s10494-022-00319-9
- Tsapenkov K.D., Kuraeva Yu.G., Sidorova E.I., Shtyrlov A.E., Zubrilin I.A. Effect of Fuel Composition on Sooting in Engines and Power Plants. Combustion, Explosion, and Shock Waves. 2024;(60):478–488. https://doi.org/10.1134/S0010508224040099
- Dhairiyasamy R., Dixit S., Varshney D., Gabiriel D. Renewable Syngas and Biodiesel Dual Fuel Applications for Enhanced Engine Performance and Emission Control. Industrial Crops and Products. 2025;225:120509. https://doi.org/10.1016/j.indcrop.2025.120509
- D S., Murugesan S., T P., A N. Experimental Investigation of Nano-Additive Enhanced Azolla Biodiesel Blends for Improved Diesel Engine Performance and Emission Mitigation. Engineering Research Express. 2025;7:015542. https://doi.org/10.1088/2631-8695/adb00b
- Martínez M., Martí-Aldaraví P., Salvador F.Ja., Martínez-Miracle E.C. In- and Near-Nozzle and External Flow Characterization in Gasoline Direct Injection (GDI) Engines – a Review of Latest Technologies and Trends. Part 2: Computational Background. International Journal of Engine Research. 2025;26(8). https://doi.org/10.1177/14680874241309959
- Paredes-Rojas Ju.C., Costa-Castelló R., Vázquez-Medina R., Flores-Campos Ju.A., Torres-San Miguel Ch.R. Experimental Study on Using Biodiesel in Hybrid Electric Vehicles. Energies. 2025;18(7):1621. https://doi.org/10.3390/en18071621
- Ayyappan K., Srinivasan D.R. Effect of Fuel Injection Pressure Variations on Engine Performance-Emission-Particulate Matter with Diesel-Iso-Butanol-Nanoparticle Fuels in Compression Ignition Engine. Indian Journal of Science and Technology. 2025;18(5):313–327. https://doi.org/10.17485/ijst/v18i5.1733
- Duan H., Hu W., Wang J., Yin X., Hu E., Zeng Ke. Effects of Diesel Pilot-Injection Strategy on a Methanol/Diesel Dual-Direct Injection Engine. Applied Thermal Engineering. 2025;261:125106. https://doi.org/10.1016/j.applthermaleng.2024.125106
- Tutak W., Lukács K., Szwaja S., Bereczky Á. Alcohol-Diesel Fuel Combustion in the Compression Ignition Engine. Fuel. 2015;154(15):196–206. https://doi.org/10.1016/j.fuel.2015.03.071
- Strizhak P.A., Antonov D.V., Aldoshin S.M., Yanovskii L.S. The Chemmotology of New Generation Synthetic Liquid Fuels. Chemistry and Technology of Fuels and Oils. 2025;60(6):1409–1418. https://doi.org/10.1007/s10553-025-01805-2
- Chłopek Z., Sar H., Szczepański K., Zakrzewska D. Operational Issues of Using Replacement Fuels to Power Internal Combustion Engines. Energies. 2023;16(6):2643. https://doi.org/10.3390/en16062643
- Markov V.A., Zenin A.A., Devyanin S.N. [Operation of a Transport Diesel Engine on Mixtures of Diesel Fuel and Methyl Ester of Rapeseed Oil]. Turbines & Diesels Magazine. 2009;(3):14–19. (In Russ.) Available at: http://www.turbine-diesel.ru/rus/node/382 (accessed 07.08.2025).
- Papalambrou G., Karystinos V. Parametric Investigation of Methanol Ratio and Diesel Injection Timing for a Marine Diesel-Methanol Dual-Fuel Engine. Journal of Marine Science and Engineering. 2025;13(4):648. https://doi.org/10.3390/jmse13040648
- Likhanov V.A., Yurlov A.S. [Investigation of the Operation of Diesel Engines Running on Methanol and Methyl Ether of Rapeseed Oil at Fuel Injection Fixer-Advanced Angles]. Vestnik Chuvashskoy gosudarstvennoy selskokhozyaystvennoy akademii. 2018;2(5):94–99. (In Russ.) Available at: http://academy21.ru/nauka-i-innovacii/vestnik-chuvashskoj-gsha-nauchnyj-zhurnal/ (accessed 15.07.2025).
- Hassan Q.H., Al-Abboodi H. How Methanol-Diesel Fuel Blends Influence the Performance
- Characteristics of a Compression Ignition Engine. International Journal of Heat and Technology. 2025;43(1):319–325. https://doi.org/10.18280/ijht.430132
- Žaglinskis Ju., Rimkus A. Research on the Performance Parameters of a Compression-Ignition Engine Fueled by Blends of Diesel Fuel, Rapeseed Methyl Ester and Hydrotreated Vegetable Oil. Sustainability. 2023;15(20):14690. https://doi.org/10.3390/su152014690
- Sánchez-Rodríguez G., Domenzaín-González J., Verónico-Sánchez F.Ja., Pérez-López H.I., Zúñiga-Moreno A., Elizalde-Solis O. Density and Viscosity in Biodiesel + Diesel Mixtures from Recycled Feedstocks. Applied Sciences. 2025;15(7):3812. https://doi.org/10.3390/app15073812
- Öner İ.V., Atabani A.E., Arslan E., Nadaroğlu H., Ünalan S., Kahraman N., et al. Comprehensive Investigation of the Effects on Fuel, Performance and Emission Properties of Modify Fuel Blends Addition of Graphene Nanoplatelets to Ternary Fuel Blends (Diesel, Waste cooking Biodiesel, and Butanol) in a Diesel Engine. Process Safety and Environmental Protection. 2025;(194):360–381. https://doi.org/10.1016/j.psep.2024.11.080

This work is licensed under a Creative Commons Attribution 4.0 License.








